Ion Chemistry Laboratory
Centre for Research in Mass Spectrometry
 York University

 

C60[X]n+ Chemistry

INtrODUCTION AND EXPLANATION OF table

This table is a collection of rate coefficients, kobs and kc, (in units of 10-9 cm3 molecule-1 s-1) measured at 296 ±2 K in helium buffer gas at 0.35 Torr using the Selected-Ion Flow Tube (SIFT) apparatus in the Ion Chemistry Laboratory at York University. The table is assembled in an alphabetical and numerical order. Ions and molecules are listed alphabetically by element according to the number of atoms of that element and the number of charges on the fullerene ion. The table is sub-divided into smaller tables according to the reactant fullerene cation. For example, the fullerene cation C60.+ makes up one sub-table of its reactions with various neutrals, C602+ makes up another, and derivatized C60 cation reactions are each listed in sub-tables. Neutral reactants within the sub-tables are organized in a similar manner. Whenever possible structural formulae are used in preference to empirical formulae for the neutrals. All of the neutrals are placed in alphabetical order. For example, Ar would come first, then molecules containing carbon, then H, etc.. All carbon-containing molecules are ordered according to the number of carbon atoms they contain. The larger the number of carbon atoms in a molecule, the further down the sub-table it is. Molecules containing the same number of carbon atoms are ordered by their number of hydrogen atoms. Molecules with an equal number of both carbon and hydrogen atoms are ordered alphabetically by the remaining atoms. For example, CH4 would precede CH30H.

For reactions with more than one product channel, branching ratios are given along with the products, when available. References are listed in chronological order.

REACTANTS PRODUCTS BR (kexp) kc kexp / kc REFERENCE
 
C56.+
NH3 C56.NH3.+ 1.0 0.0096 1.7 0.01 16
 
C562+
CH3CN C56.CH3CN2+ 1.0 4.3 5.0 0.87 16
C2H4 C56.C2H42+ 1.0 0.021 1.9 0.01 16
n-C4H10 C56H+ + C4H9+ 1.0 0.027 1.9 0.01 16
 
C58.+
NH3 C58.NH3.+ 1.0 0.034 1.7 0.02 16
 
C582+
CH3CN C58.CH3CN2+ 1.0 4.2 4.9 0.85 16
C2H4 C58.C2H42+ 1.0 0.019 1.9 0.01 16
n-C4H10 C58H+ + C4H9+ 1.0 0.034 1.9 0.02 16
 
C60
Ar.+ C60.+ + Ar 1.0 2
C20H10.+ C20H10.+.C60 0.6 0.6 1.4 0.43 17
(corannulene) C20H10 + C60.+ 0.4 0.4
D+ C60.+ + D. 14 8
He.+ C60.+ + He <0.90 <0.90 10 2
C602+ + He + e >0.10 >0.10
Ne.+ C60.+ + Ne <0.95 <0.95 2
C602+ + Ne + e >0.05 >0.05
Si.+ C60.+ + Si 0.4 0.4 3.9 0.10 1
C60.Si.+ 0.6 0.6
C60.+
HCN none 1.0 <0.001 15
H2CO none 1.0 <0.001 22
HCOOH none 1.0 <0.001 22
CH4 none 1.0 <0.001 5
CH3OH none 1.0 <0.001 14
CH3NH2 C60.CH3NH2.+ 1.0 0.015 1.4 0.01 12
CO none 1.0 <0.001 5
COS none 1.0 <0.001 5
CO2 none 1.0 <0.001 5
C2H2 none 1.0 <0.001 0.89 5
CH3CN none 1.0 <0.001 15
CH3NC none 1.0 <0.001 U
C2H4 none 1.0 <0.001 5
C2H4O none 1.0 ~0.0003 18
CH3CHO none 1.0 <0.001 22
c-CH2OCH2 none 1.0 <0.001 U
CH3COOH none 1.0 <0.01 22
HCOOCH3 none 1.0 <0.001 22
C2H6 none 1.0 <0.001 5
CH3CH2OH none 1.0 <0.001 14
(CH3)2O none 1.0 <0.001 14
CH3CH2NH2 C60.CH3CH2NH2.+ 1.0 0.05 1.3 0.04 12
(CH3)2NH C60.(CH3)2NH.+ 1.0 0.85 1.2 0.70 12
NCCN none 1.0 <0.001 15
CH2(CN)2 none 1.0 <0.01 15
CH2CHCN none 1.0 <0.001 15
CH2CCH2 none 1.0 <0.001 5
CH3CCH none 1.0 <0.001 5
CH3CH2CN none 1.0 <0.001 15
CH3CHCH2 none 1.0 <0.001 5
CH3CH2CHO none 1.0 <0.001 22
CH3COCH3 none 1.0 <0.001 22
c-CH2OCHCH3 none 1.0 <0.001 U
CH3COOCH3 none 1.0 <0.001 22
C3H8 none 1.0 5
CH3CH2CH2OH none 1.0 <0.01 14
(CH3)2CHOH none 1.0 <0.01 14
(CH3)3N C60.(CH3)3N.+ 1.0 1 1.05 0.95 12
CH3COCCH none 1.0 <0.001 22
C4H4O none 1.0 <0.0002 1.3 21
(furan)
CH2CHCH2CN none 1.0 <0.001 U
CH2CHCHCH2 none 1.0 <0.001 5, 7
(1,3-butadiene)
CH3CH2CH2CN none 1.0 <0.01 15
(CH3)2CHCN none 1.0 <0.01 15
n-C3H7CN none 1.0 <0.01 15
1-C4H8 none 1.0 <0.001 5
(Z)-2-C4H8 none 1.0 <0.001 5
(CH3)2CCH2 none 1.0 <0.001 5
c-CH2OCHC2H5 none 1.0 <0.01 U
c-(CH2)4O none 1.0 <0.001 14
CH3COCH2CH3 none 1.0 <0.001 22
n-C4H10 none 1.0 <0.001 5
i-C4H10 none 1.0 <0.001 5
C2H5OC2H5 none 1.0 <0.001 14
c-C5H6 C60.C5H6.+ 1.0 0.01 0.93 0.01 21
 
(1,3-cyclopentadiene)
CH2CCH3CHCH2 none 1.0 <0.0005 0.93 21
 
(isoprene)
CH3CH2CHCCH2 none 1.0 <0.002 0.93 21
(1,3-pentadiene) 1.0
C5H8 none 1.0 <0.002 0.91 21
(cyclopentene) 1.0
c-(CH2)4CO none 1.0 <0.01 22
CH3COCH2CH2CH3 none 1.0 <0.01 22
CH3CH2COCH2CH3 none 1.0 <0.01 22
C6H6 none 1.0 <0.001 5
C6H8 C60.C6H8.+ 1.0 0.015 1 0.02 21
(1,3-cyclohexadiene) 1.0
C6H8 none 1.0 <0.003 0.9 21
(1,4-cyclohexadiene) 1.0
C6H10 none 1.0 <0.002 0.9 21
(cyclohexene) 1.0
C10H8 none 1.0 <0.01 8
C20H10 C60.+.C20H10 0.9 0.9 17
(corannulene) C20H10.+ + C60 0.1
D. C60D+ 1.0 >0.3 1.4 3
D2 none 1.0 <0.001 1 3
H. C60H+ 1.0 >0.1 1.9 3
H2 none 1.0 <0.001 1.5 3
H2O none 1.0 <0.01 14
NH3 C60.NH3.+ 1.0 <0.001 1.7 12
NO none 1.0 <0.001 8
NO2 none 1.0 <0.001 5
N2 none 1.0 <0.001 5
N2O none 1.0 <0.001 5
O2 none 1.0 <0.001 5
 
C602+
HCN none 1.0 <0.001 4.2 9
H2CO none 1.0 <0.001 3.4 9
HCOOH C60.HCOOH2+ 1.0 0.015 2.2 0.01
CH4 none 1.0 <0.001 1.9 4
CH3OH C60.OHCH32+ 1.0 0.007 2.9 0.002 9
CH3NH2 C60.NCH3H22+ 1.0 0.9 2.9 0.31 2, 4
C60.+ + CH3NH2.+ 1.0
CO none 1.0 5
COS none 1.0 1.7 4
CO2 none 1.0 5
C2H2 C60.C2H22+ 1.0 <0.001 <0.002 4
CH3CN C60.NCCH32+ 1.0 0.08 4.7 9
CH3NC C60.CH3NC2+ 1.0 <0.001 <0.002 4
C2H4 C60.C2H42+ 1.0 <0.001 <0.002 9
CH3CHO none 1.0
c-CH2OCH2 1.0 x x U
C2H4O C60.C2H4O2+ 1.0 0.053 1.1 18
(observed additions up to
6 molecules of C2H4O to C602+)		 1.0
CH3COOH C60.CH3COOH2+ 1.0 0.4 2.4 0.17 9
HCOOCH3 C60.HCOOCH32+ 1.0 0.011 2.4 0.005
C2H6 none 1.0 1.8 4
CH3CH2OH C60.OHC2H52+ 0.9 0.037 2.8 0.013 9
C60OH+ + C2H5+ 0.1
CH3OCH3 C60.(CH3)2O2+ 1.0 0.003 2.5 0.001 14
(CH3)2NH C60.NH(CH3)22+ 0.10 2.9 2.4 1.2 9
C60.+ + (CH3)2NH.+ 0.90
CH3CH2NH2 C60.NCH3CH2H22+ 0.70 2.6 2.7 0.97 9
C60.+ + CH3CH2NH2.+ 0.30
NCCN C60.NCCN2+ 1.0 <0.001 1.9 15
CH2(CN)2 none 1.0 <0.01 3.6 15
CH2CHCN C60.NCC2H32+ 1.0 0.07 4.5 0.016 9
CH2CCH2 C60.C3H42+ 1.0 0.08 1.9 0.043 4
CH3CCH C60.C3H42+ 1.0 0.5 2.3 0.22 4
CH3CH2CN C60.NCC2H52+ 1.0 2.5 4.4 0.57 9
CH3CHCH2 C60.C3H62+ 1.0 1.3 2.0 0.66 5
CH3CH2CHO C60.C2H5CHO2+ 1.0 0.06 3.2 0.019 22
CH3COCH3 C60.(CH3)2CO2+ 1.0 0.27 3.4 0.079 9
c-CH2OCHCH3 x 1.0 x x U
CH3COOCH3 C60.CH3COOCH32+ 1.0 0.016 2.3 0.007 22
C3H8 C60H+ + C3H7+ 1.0 0.002 1.9 0.001 5
n-CH3CH2CH2OH C60.C3H7OH2+ 0.6 0.1 2.5 0.040 14
C60OH+ + C3H7+ 0.4 14
i-(CH3)2CHOH C60OH+ + C3H7+ 1.0 0.23 2.6 0.090 14
(CH3)3N C60.+ + (CH3)3N.+ 2.2 2.1 9
CH3COCCH C60.CH3COCCH2+ 1.0 0.13 2.9 0.04 22
CH2CHCH2CN C60.NCC3H52+ 1.0 1.8 3.9 0.47 15
CH2CHCHCH2 C60.C4H62+ 0.8 1 1.9 0.52 7
(1,3-butadiene) C60.+ + C4H6.+ 0.2
(observed additions up to
6 molecules of C4H6 to C602+)
CH3CH2CH2CN C60.NCC3H72+ 1.0 3.9 4.2 0.94 15
(CH3)2CHCN C60.NCC3H72+ 1.0 4.3 3.9 1.09 15
1-C4H8 C60.C4H82+ 1.0 2.2 1.9 1.13 4
(Z)-2-C4H8 C60.C4H82+ 0.2 3.4 2.0 1.73 4
C60.+ + C4H8.+ 0.8
(CH3)2CCH2 C60.C4H82+ 0.9 2.4 2.03 1.2 4
C60.+ + C4H8.+ 0.1
c-(CH2)4O C60.C4H8O2+ 0.6 1.9 2.5 0.76 14
C60.+ + c-C4H8O.+ 0.4
CH3COCH2CH3 C60.CH3COC2H52+ 1.0 1.2 3.06 0.39 9
c-CH2OCHC2H5 x 1.0 x x U
n-C4H10 C60H+ + C4H9+ 1.0 <0.001 1.9 5
i-C4H10 C60H+ + C4H9+ 1.0 0.025 1.9 0.01 5
(C2H5)2O C60.(C2H5)2O2+ 1.0 0.91 2.3 0.40 14
C60.+ + C4H10O.+ 0.9
c-C5H6 C60.+ + C5H6.+ 1.0 fast 1.9 8
c-(CH2)4CO C60.C5H8O2+ 0.3 2.8 3.3 0.85 22
C60.+ + C5H8O.+ 0.7
C2H5COC2H5 C60.(C2H5)2CO2+ 0.75 1.9 3.0 0.64 22
C60.+ + C5H10O.+ 0.25
CH3COC3H7 C60.CH3COC3H72+ 0.9 1.8 3.0 0.60 22
C60.+ + C5H10O.+ 0.1
C6H6 C60.+ + C6H6.+ 1.0 2.3 1.8 1.3 4
C10H8 C60.+ + C10H8.+ 1.0 9 1.9 4.7 8
C14H10 C60.+ + C14H10.+ 1.0 obs 2.05 6
C20H10 (corannulene) C60.+ + C20H10.+ 1.0 x 1.8 17
C60 C60.+ + C60.+ 1.0 obs 2.1 6
D. C60D2.+ 1.0 >0.3 2.7 3
D2 none 1.0 <0.001 2.1 3
H. C60H2.+ 1.0 >0.3 3.8 3
H2 none 1.0 <0.001 3.1 3
H2O none 1.0 <0.01 3.4 9
NH3 C60.NH32+ 1.0 1.2 3.4 0.36 4
NO. C60.+ + NO+ 1.0 0.02 1.2 0.017 4
NO2 none 1.0 <0.001 - 4
NO2. none 1.0 <0.01 1.35 4
N2 none 1.0 <0.001 - 5
N2O none 1.0 <0.001 1.3 4
O2 none 1.0 <0.001 1.06 4
 
C603+
CH3Cl C60H.2+ + CH2Cl+ 1.0 obs 4.0 11
HCN C60.NCH.3+ 1.0 2.5 6.4 0.39 15
H2CO C602+ + H2CO.+ 1.0 1.8 5.1 0.36 22
HCOOH C60H.2+ + CO2H+ 0.5 2.5 3.3 0.75 11
C60.HCOOH.3+ 0.5
CH3NO2 C60.CH3NO2.3+ 0.9 5 5.6 0.89 11
C602+ + CH3NO2.+ 0.1
CH4 none 1.0 <0.0001 2.9 U
CH3OH C602+ + CH3OH.+ 0.8 2.5 4.4 0.57 11
C60.CH3OH.3+ 0.2
CH3NH2 C602+ + CH3NH2.+ 1.0 3.8 4.3 0.88 12
COS C602+ + COS.+ 1.0 0.048 2.6 0.018 11
C2H2 C60.C2H2.3+ 1.0 0.15 2.7 0.056 11
CH3CN C60.NCCH3.3+ 1.0 5.9 7.0 0.84 15
CH3NC C60.CH3NC.3+ 1.0 x x U
C2H4 C60.C2H4.3+ 0.4 1.7 2.8 0.61 U
C602+ + C2H4.+ 0.6
CH3CHO C602+ + CH3CHO.+ 1.0 3.7 5.1 0.73 22
c-CH2OCH2 x 1.0 x x U
CH3COOH C60.CH3COOH.3+ 1.0 4.2 3.6 1.16 22
HCOOCH3 C60.HCOOCH3.3+ 1.0 2.9 3.7 0.79 22
C2H6 none 1.0 <0.005 2.8 11
CH3CH2OH C60OH.2+ + C2H5+ 0.7 2.4 4.2 0.58 14
C602+ + C2H5OH.+ 0.2
C60.C2H5OH.3+ 0.1
CH3OCH3 C602+ + CH3OCH3.+ 1.0 3 3.7 0.81 14
CH3CH2NH2 C602+ +CH3. +CH2NH2+ >0.90 3.4 4.02 0.85 12
C602+ + CH3CH2NH2.+ <0.10
(CH3)2NH C602+ + (CH3)2NH.+ 1.0 3.5 3.7 0.96 12
NCCN C60.NCCN.3+ 1.0 0.01 2.9 0.004 15
CH2(CN)2 C60.NCCH2CN.3+ 1.0 5.6 5.5 1.03 15
CH2CHCN C60.NCC2H3.3+ 0.9 4 6.8 0.59 15
C602+ + C2H3CN.+ 0.1
CH2CCH2 C602+ + C3H4.+ 1.0 x 2.8 U
CH3CH2CN C60.NCC2H5.3+ 1.0 4 6.6 0.60 15
CH3CHCH2 C602+ + C3H6.+ 1.0 x 3 U
CH3CH2CHO C602+ + C2H5CHO.+ 0.75 4.2 4.7 0.89 22
C60.C2H5CHO.3+ 0.25
CH3COCH3 C602+ + (CH3)2CO.+ 1.0 5.8 5.1 1.1 22
c-CH2OCHCH3 x x x U
CH3COOCH3 C60.CH3COOCH3.3+ 0.9 3.4 3.5 0.97 22
C602+ + C3H6O2.+ 0.1
C3H8 C60H.2+ + C3H7+ 0.9 4.2 2.8 1.48 11
C602+ + C3H8.+ 0.1
CH3CH2CH2OH C602+ + C3H7OH.+ 0.5 3.9 3.8 1.03 14
C60OH.2+ + C3H7+ 0.4
C60.C3H7OH.3+ 0.1
(CH3)2CHOH C60OH.2+ + C3H7+ 0.7 4.1 3.8 1.07 14
C602+ + C3H7OH.+ 0.3
(CH3)3N C602+ + (CH3)3N.+ 1.0 2.8 3.2 0.89 12
CH3COCCH C602+ + C4H4O.+ 0.8 4.5 4.3 1.04 22
C60.CH3COCCH.3+ 0.2
CH2CHCH2CN C60.NCC3H5.3+ 0.6 6.6 5.8 1.1 15
C602+ + C3H5CN.+ 0.4
CH3CH2CH2CN C60.NCC3H7.3+ 1.0 6.3 6.2 1.01 15
(CH3)2CHCN C60.NCC3H7.3+ 1.0 4.8 5.9 0.81 15
c-CH2OCHC2H5 x 1.0 x x U
CH3COCH2CH3 C602+ + CH3COC2H5.+ 1.0 5.6 4.6 1.22 22
c-(CH2)4O C602+ + c-C4H8O.+ 1.0 3.3 3.8 0.88 14
(C2H5)2O C602+ + (C2H5)2O.+ 1.0 3.3 3.5 0.96 14
c-(CH2)4CO C602+ + c-C5H8O.+ 1.0 4.3 5.0 0.87 22
CH3COC3H7 C602+ + CH3COC3H7.+ 1.0 4.8 4.5 1.07 22
C2H5COC2H5 C602+ + (C2H5)2CO.+ 1.0 5.5 4.5 1.2 22
C6H6 C602+ + C6H6.+ 1.0 x 2.7 U
C10H8 C602+ + C10H8.+ 1.0 x 2.7 U
C14H10 C602+ + C14H10.+ >0.95 obs 3 U
(anthracene) C60.+ + C14H102+ <0.05
C16H10 C602+ + C16H10.+ >0.95 obs 2.8 U
(pyrene) C60.+ + C16H102+ <0.05
C20H10 C602+ + C20H10.+ ~0.99 2.7 17
(corannulene) C60.+ + C20H102+ ~0.01
 
C24H14 C602+ + C24H14.+ 0.6 obs 3 U
(benzo[rst]penta- C60.+ + C24H142+ 0.4
phene)
Cl2 C60Cl.2+ + Cl+ obs 1.89 11
H2O C60H2+ + OH+ 0.2 4.54 14
H2S C60H.2+ + HS+ >0.5 3.5 3.4 1.03 11
C602+ + H2S.+ <0.5
NH3 C60.NH3.3+ 3.9 5.04 12
NO. C602+ + NO+ 1.1 1.67 11
O2 none 1.0 <0.001 1.6 11
 
C60.HCOOH2+
HCOOH C60.HCOO+ + HCOOH2+ 1.0 >1.0 10
 
C60.CH3OH2+
CH3OH C60.CH3O+ + CH3OH2+ 1.0 >1.0 - 10
 
C60.CH3NH22+
CH3NH2 C60.CH3NH+ + CH3NH3+ 1.0 >1.0 - 10
C60.(CH3NH2)22+ 1.0
 
C60.(CH3NH2)22+
CH3NH2 C60.CH3NH2.CH3NH+ + CH3NH3+ 1.0 >1.0 - 10
 
C60.CH3CN2+
CH3CN C60.(CH3CN)22+ 1.0 0.12 - 15
 
C60.(CH3CN)22+
CH3CN C60.(CH3CN)32+ 1.0 <0.005 - 15
 
C60.C2H4O2+
C2H4O C60.(C2H4O)22+ 1.0 >0.5 - 18
 
C60.CH3COOH2+
CH3COOH C60.CH3COO+ + CH3COOH2+ 1.0 >1.0 - 10
C60.(CH3COOH)22+ 1.0
C60.C2H5OH2+
 
C2H5OH C60.C2H5O+ + C2H5OH2+ 1.0 >1.0 - 10
 
C60.C2H5NH22+
C2H5NH2 C60.C2H5NH+ + C2H5NH3+ 1.0 >1.0 - 10
C60.(C2H5NH2)22+ 1.0
C60.(C2H5NH2)22+
C2H5NH2 C60.C2H5NH2.C2H5NH+ + C2H5NH3+ 1.0 >1.0 - 10
 
C60.(CH3)2NH2+
(CH3)2NH C60.(CH3)2N+ + (CH3)2NH2+ 1.0 >1.0 - 10
 
C60.C2H3CN2+
C2H3CN C60.(C2H3CN)22+ 1.0 0.13 - 15
 
C60.(C2H3CN)22+
C2H3CN C60.(C2H3CN)32+ 1.0 <0.005 - 15
 
C60.C2H5CN2+
C2H5CN C60.(C2H5CN)22+ 1.0 2.2 - 15
 
C60.(C2H5CN)22+
C2H5CN C60.(C2H5CN)32+ 1.0 0.034 - 15
 
C60.(C2H5CN)32+
C2H5CN C60.(C2H5CN)42+ 1.0 <0.05 - 15
 
C60.(CH3)2CO2+
(CH3)2CO C60.CH3COCH2+ + CH3COCH4+ 1.0 >1.0 - 10
C60.((CH3)2CO)22+
 
C60.((CH3)2CO)22+
(CH3)2CO C60.CH3COCH3.CH3COCH2+ + CH3COCH4+ 1.0 >1.0 - 10
 
C60.C3H5CN2+
C3H5CN C60.(C3H5CN)22+ 1.0 1.9 - 15
 
C60.(C3H5CN)22+
C3H5CN C60.(C3H5CN)32+ 1.0 0.08 - 15
C60.(C3H5CN)32+
C3H5CN C60.(C3H5CN)42+ 1.0 <0.05 - 15
 
C60.n-C3H7CN2+
CH3CH2CH2CN C60.(n-C3H7CN)22+ 1.0 4.6 - 15
 
C60.(n-C3H7CN)22+
CH3CH2CH2CN C60.(n-C3H7CN)32+ 1.0 0.38 - 15
 
C60.(n-C3H7CN)32+
CH3CH2CH2CN C60.(n-C3H7CN)42+ 1.0 <0.1 - 15
 
C60.i-C3H7CN2+
(CH3)2CHCN C60.(i-C3H7CN)22+ 1.0 3.6 - 15
 
C60.(i-C3H7CN)22+
(CH3)2CHCN C60.(i-C3H7CN)32+ 1.0 0.16 - 15
 
C60.(i-C3H7CN)32+
(CH3)2CHCN C60.(i-C3H7CN)42+ 1.0 <0.1 - 15
 
C60.CH3COC2H52+
CH3COC2H5 C60.CH3COC2H4+ + CH3COC2H6+ 1.0 >1.0 - 10
C60.(CH3COC2H5)22+
 
C60.(CH3COC2H5)22+
CH3COC2H5 C60.CH3COC2H5.CH3COC2H4+ + CH3COC2H6+ 1.0 >1.0 10
 
C60D+
D. C60D2.+ 1.0 obs 1.4 3
C60D.2+
D. C60D22+ 1.0 obs 2.7 3
C60D22+
D.
C60D3.2+ 1.0 obs 2.7 3
C60D3.2+
D. C60D42+ 1.0 obs 2.7 3
C60H.2+
HCN C60.+ + HCNH+ 1.0 0.14 4.2 0.03 13
H2CO C60.+ + H2COH+ 1.0 0.34 3.5 0.10 13
HCOOH C60.+ + HCOOH2+ 1.0 3.2 2.3 1.4 13
CH3NO2 C60.+ + CH3NO2H+ 1.0 1.2 3.7 0.32 13
CH3OH C60.+ + CH3OH2+ 1.0 1.9 2.9 0.65 13
CO none 1.0 <0.001 1.3 13
CS2 none 1.0 <0.001 1.7 13
C2H2 none 1.0 <0.001 1.8 13
C2H4 none 1.0 <0.001 1.9 13
CH2(CN)2 C60.+ + NCCH2CNH+ 1.0 0.45 3.6 0.12 13
CH2CHCN C60.+ + C2H3CNH+ 1.0 7 4.51 1.6 13
C3H8 C60H2.+ + C3H7+ 1.0 0.0015 1.9 0.001 13
i-C4H10 C60H2.+ + C4H9+ 1.0 0.015 1.8 0.0082 13
H2S C60H2.+ + HS+ 1.0 0.008 2.3 0.004 13
NOC C60H+ + NO+ 1.0 0.015 1.2 0.013 13
O2 none 1.0 <0.001 1.1 13
C60.NH32+
NH3 C60.NH2+ + NH4+ 1.0 >1.0 - 10
C60.(NH3)22+
C60.(NH3)22+
NH3 C60.NH3.NH2+ + NH4+ 1.0 >1.0 - 10
C70.+
CH4 none 1.0 <0.001 - 1
CH3NH2 C70.CH3NH2.+ 1.0 <0.01 1.4 1
CO none 1.0 <0.001 - 1
COS none 1.0 <0.001 - 1
CO2 none 1.0 <0.001 - 1
C2H2 none 1.0 <0.001 - 1
C2H4 none 1.0 <0.001 - 1
C2H6 none 1.0 <0.001 - 1
(CH3)2O none 1.0 <0.001 1
(CH3)2NH C70.(CH3)2NH.+ 1.0 obs 1.2 1
CH3CH2NH2 C70.CH3CH2NH2.+ 1.0 obs 1.3 1
CH3CCH none 1.0 <0.001 1
CH2CCH2 none 1.0 <0.001 1
(CH3)3N C70.(CH3)3N.+ 1.0 obs 1.05 1
CH2CHCHCH2 none 1.0 <0.001 1, 7
(1,3-butadiene)
c-C5H6 C70.C5H6.+ 1.0 0.002 1 0.002 1, 21
C6H6 none 1.0 <0.001 - 1
C10H8 none 1.0 <0.01 - 1
D. C70D+ 1.0 obs 1.4 3
D2 none 1.0 <0.001 1 3
H. C70H+ 1.0 obs 1.9 3
H2 none 1.0 <0.001 1.5 3
H2O none 1.0 <0.01 - 1
NH3 C70.NH3.+ 1.0 <0.001 1.7 1
NO none 1.0 <0.001 - 1
N2 none 1.0 <0.001 - 1
O2 none 1.0 <0.001 - 1
C702+
HCN none 1.0 <0.001 4.2 15
CH4 none 1.0 <0.001 1.9 4
CH3NH2 C70.CH3NH22+ 0.90 obs 2.9 1
C70.+ + CH3NH2.+ 0.10
CO none 1.0 <0.001 - 5
COS none 1.0 <0.001 1.7 4
CO2 none 1.0 <0.001 - 5
C2H2 C70.C2H22+ 1.0 <0.001 1.8 4
CH3CN C70.NCCH32+ 1.0 0.029 4.7 0.0062 15
CH3NC C70.CH3NC2+ 1.0 x x U
C2H4 C70.C2H42+ 1.0 <0.001 1.9 4
C2H6 none 1.0 <0.001 1.8 4
(CH3)2NH C70.(CH3)2NH+ 0.10 obs 2.4 1
C70.+ + (CH3)2NH.+ 0.90
CH3CH2NH2 C70.CH3CH2NH22+ 0.70 obs 2.7 1
C70.+ + CH3CH2NH2.+ 0.30
C2N2 C70.NCCN2+ 1.0 <0.001 1.9 15
CH2(CN)2 none 1.0 <0.01 3.6 15
CH2CHCN C70.NCCH2CH2+ 1.0 0.04 4.5 0.0089 15
CH2CCH2 C70.C3H42+ 1.0 0.009 1.8 0.0049 4
CH3CCH C70.C3H42+ 1.0 0.03 2.3 0.013 4
CH3CH2CN C70.NCC2H52+ 1.0 1.6 4.4 0.36 15
CH3CHCH2 C70.C3H62+ 1.0 >0.4 2.0 4
(CH3)2CN C70.(CH3)2CN2+ 1.0 3.4 4.6 0.74 U
C3H8 none 1.0 <0.001 1.9 1
(CH3)3N C70.+ + (CH3)3N.+ 1.0 obs 2.1 1
CH2CHCH2CN C70.NCC3H52+ 1.0 0.77 3.9 0.20 15
CH2CHCHCH2 C70.C4H62+ >0.5 1 1.9 0.53 7
(1,3-butadiene) C70+ + C4H6.+ 1.0 <0.5
(observed additions up to
3 molecules of C4H6 to C702+)
n-C3H7CN C70.NCC3H72+ 1.0 3 4.2 0.72 15
(CH3)2CHCN C70.NCC3H72+ 1.0 3.4 3.9 0.87 15
1-C4H8 C70.C4H82+ 1.0 1.8 1.9 0.93 4
(Z)-2-C4H8 C70.C4H82+ x 2 2.0 1.03 4
C70.+ + C4H8.+ x
(CH3)2CCH2 C70.C4H82+ 1.0 0.3 2.01 0.15 4
n-C4H10 none 1.0 <0.001 1.9 5
i-C4H10 none 1.0 <0.001 1.9 5
c-C5H6 C70.+ + C5H6.+ 1.0 fast 1.9 8
C6H6 C70.+ + C6H6.+ 1.0 0.14 1.8 0.078 4
C10H8 C70.+ + C10H8.+ 1.0 10 1.9 5.3 6
C14H10 C70.+ + C14H10.+ 1.0 obs 2.02 6
C60 C70.+ + C60.+ 1.0 obs 2.07 6
D. C70D.2+ 1.0 obs 2.7 3
D2 none 1.0 <0.001 2.1 3
H. C70H.2+ 1.0 obs 3.8 3
H2 none 1.0 <0.001 3.09 3
H2O none 1.0 <0.001 8
NH3 C70.NH32+ 1.0 0.7 3.4 0.21 1, 4
NO. C70.+ + NO+ 1.0 <0.001 1.2 4
NO2 none 1.0 <0.01 1.4 4
NO2. none 1.0 <0.001 - 5
N2 none 1.0 <0.001 - 5
N2O none 1.0 <0.001 1.3 4
O2 none 1.0 <0.001 1.06 4
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References [1] PAH and Fullerene Ions and Ion/Molecule Reactions in Interstellar and Circumstellar Chemistry.
D.K. Bohme, Chem. Rev., 1992, 92, 1487-1508.

[2] Fullerene cation and dication production by novel thermal energy reactions of He+, Ne+, and Ar+ with C60.
G. Javahery, S. Petrie, J. Wang and D.K. Bohme, Chem. Phys. Lett., 1992, 1, 7-10.

[3] Hydrogenation of Fullerene Cations in the Gas Phase: Reactions of Fullerene Cations and Dications with Atomic and Molecular Hydrogen.
S. Petrie, G. Javahery, J. Wang, and D.K. Bohme, J. Am. Chem. Soc., 1992, 114, 6268-6269.

[4] Selected-Ion Flow Tube Study of Charge Transfer from Fullerene Dications: "Bracketing" the Second Ionization Energies of C60 and C70.
S. Petrie, G. Javahery, J. Wang and D.K. Bohme, J. Phys. Chem., 1992, 96, 6121-6123.

[5] Derivatization of the Fullerene Dications C602+ and C702+ by Ion Molecule Reactions in the Gas-Phase.
S. Petrie, G. Javahery, J. Wang and D.K. Bohme, J. Am. Chem. Soc., 1992, 114, 9177-9181.

[6] Charge-Transfer Reactions of Fullerene Dications with Aromatic Hydrocarbon and Fullerene Molecules in the Gas-Phase.
G. Javahery, S. Petrie, J. Wang and D.K. Bohme, Int. J. Mass Spectrom. Ion Processes, 1992, 120, R5-R9.

[7] Fullerene Dications as Initiators of Polymerization with 1,3-Butadiene in the Gas Phase: Chemistry Directed by Electrostatics.
J. Wang, G. Javahery, S. Petrie, and D.K. Bohme, J. Am. Chem. Soc., 1992, 114, 9665-9666.

[8] Experimental results for ion-molecule reactions of fullerenes: implications for interstellar and circumstellar chemistry.
S. Petrie, G. Javahery and D.K. Bohme, Astron. Astrophys., 1993, 271, 662-674.

[9] Attaching Handles to C602+ - The Double-Derivatization of C602+.
S. Petrie, G. Javahery, and D.K. Bohme, J. Am. Chem. Soc., 1993, 115 1445-1450.

[10] First steps towards a gas-phase acidity ladder for derivatized fullerene dications.
S. Petrie, G. Javahery and D.K. Bohme, Int. J. Mass Spectrom. Ion Processes, 1993, 124, 145-156.

[11] Charge-transfer reactions of C603+: "bracketing" the third ionization energy of C60.
G. Javahery, H. Wincel, S. Petrie and D.K. Bohme, Chem. Phys. Lett., 1993, 204, 467-472.

[12] Experimental-Study of Reactions of the Buckminsterfullerene Cations C60+, C602+, and C603+ with Ammonia and Amines in the Gas Phase.
G. Javahery, S. Petrie, H. Wincel, J. Wang and D.K. Bohme, J. Am. Chem. Soc., 1993, 115, 5716-5722.

[13] Proton Transfer from a Fullerene Dication: Bracketing the Gas-Phase Acidity of C60H2+.
S. Petrie, G. Javahery, H. Wincel and D.K. Bohme, J. Am. Chem. Soc., 1993, 115, 6290-6294.

[14] Gas-Phase Reactions of the Buckminsterfullerene Cations C60+, C602+, and C603+ with Water, Alcohols and Ethers.
G. Javahery, S. Petrie, H. Wincel, J. Wang and D.K. Bohme, J. Am. Chem. Soc., 1993, 115, 6295-6301.

[15] Gas-Phase Reactions of Fullerene Monocations, Dications, and Trications with Nitriles.
G. Javahery, S. Petrie, J. Wang, H. Wincel and D.K. Bohme, J. Am. Chem. Soc., 1993, 115, 9701-9707.

[16] Enhanced reactivity of fullerene cations containing adjacent pentagons.
S. Petrie and D.K. Bohme, Nature, 1993, 365, 426-429.

[17] Gas-Phase Ion/Molecule Reactions of Corannulene, a Fullerene Subunit.
H. Becker, G. Javahery, S. Petrie, P. Cheung, H. Schwarz, L.T. Scott and D.K. Bohme, J. Am. Chem. Soc., 1993, 115, 11636-11637.

[18] Fullerene Dications as Initiators for Gas-Phase "Ball-and-Chain" Polymerization of Ethylene Oxide; Termination by Cyclization.
J. Wang, G. Javahery, S. Petrie, A.C. Hopkinson and D.K. Bohme, Angew. Chem. Int. Ed. Engl., 1994, 33, 206-207.

[19] Gas-phase association reactions of fullerene cations: modelling the influence of charge state and other molecular parameters on association effeciency.
S. Petrie and D.K. Bohme, Can. J. Chem., 1994, 72, 577-586.

[20] Electron-transfer reactions with buckminsterfullerene, C60, in the gas phase.
D.K. Bohme, Int. Rev. Phys. Chem., 1994, 13, 163-185.

[21] [4+2+] Diels-Alder Cycloaddition to C60 and C70 Radical Cations in the Gas Phase: A Comparison with Solution.
H. Becker, G. Javahery, S. Petrie and D.K. Bohme, J. Phys. Chem., 1994, 98, 5591-5592.

[22] Gas-phase reactions of the buckminsterfullerene cations C60+, C602+, and C603+ with aldehydes, ketones, carboxylic acids and esters.
S. Petrie, G. Javahery, H. Wincel, J. Wang and D.K. Bohme, Int. J. Mass Spectrom. Ion Processes, 1994, 138, 187-208.
Ion Chemistry Laboratory, York University 4700 Keele Street, Toronto, Ontario M3J 1P3