|
Precise
isotope shift and fine structure measurements are critically reviewed.
Each experiment
was checked whether data found for different transitions yielded
consistent values for the relative nuclear charge radius squared ∆r2
of 6,7Li. Experiments that passed this test found ∆r2
= 0.735 ± 0.036, 0.755 ± 0.023 and 0.739 ± 0.013 fm2 by
studying the Li+ 1s2s 3S1 1s2p 3P
transition, the Li D lines and the Li 2S1/2 - 3S1/2
transition, respectively. These data determine the relative nuclear charge
radius 25 times more accurately than electron scattering. Similarly,
averaging the most reliable fine structure data gives 62,678.75 ± 0.55
MHz for the 7Li+ 1s2p 3P1,2
interval in good agreement with theory. The results for the 6,7Li
2P fine structure intervals, 10,052.954 ± 0.049 and 10,053.154 ± 0.040
MHz, exceed computed values by 2 MHz and yield a specific isotope shift
which is nearly a factor of 2 lower than a theoretical estimate.
|