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PUBLICATION ABSTRACTS, W. van Wijngaarden           2009

Critical Examination of Isotope Shift and Fine Structure Measurements for Optical Transitions in 6,7Li [PDF]
G. A. Noble and W. A. van Wijngaarden
In Press. Canadian Journal Of Physics 

Precise isotope shift and fine structure measurements are critically reviewed.
E
ach experiment was checked whether data found for different transitions yielded consistent values for the relative nuclear charge radius squared ∆r2 of 6,7Li. Experiments that passed this test found ∆r2 = 0.735 ± 0.036, 0.755 ± 0.023 and 0.739 ± 0.013 fm2 by
studying the Li+ 1s2s 3S1 1s2p 3P transition, the Li D lines and the Li 2S1/2 - 3S1/2
transition, respectively. These data determine the relative nuclear charge radius 25 times more accurately than electron scattering. Similarly, averaging the most reliable fine structure data gives 62,678.75 ± 0.55 MHz for the 7Li+ 1s2p 3P1,2 interval in good agreement with theory. The results for the 6,7Li 2P fine structure intervals, 10,052.954 ± 0.049 and 10,053.154 ± 0.040 MHz, exceed computed values by 2 MHz and yield a specific isotope shift which is nearly a factor of 2 lower than a theoretical estimate.